Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb⋅DTMA]<sup>3+</sup> in Aqueous Solution.

Blackburn OA, Chilton NF, Keller K, Tait CE, Myers WK, McInnes EJL, Kenwright AM, Beer PD, Timmel CR, Faulkner S
September 2015
Journal article
Journal:
Angewandte Chemie (Weinheim an der Bergstrasse, Germany)
Volume:
127
Issue:
37
,
pp.
10933 - 10936

Yb⋅DTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [Yb⋅DTMA⋅F]2+ and [Yb⋅DTMA⋅OH2]3+ are in slow exchange on the relevant NMR timescale (

DOI
10.1002/ange.201503421